{"id":998922,"date":"2024-06-17T13:59:10","date_gmt":"2024-06-17T05:59:10","guid":{"rendered":"https:\/\/vimaterial.de\/product\/lithium-manganese-iron-phosphate\/"},"modified":"2026-08-06T11:34:19","modified_gmt":"2026-08-06T03:34:19","slug":"lithium-manganese-iron-phosphate-powder","status":"publish","type":"product","link":"https:\/\/vimaterial.de\/en\/product\/lithium-manganese-iron-phosphate-powder\/","title":{"rendered":"Lithium Manganese Iron Phosphate (LMFP)"},"content":{"rendered":"<p>Lithium manganese iron phosphate powder is an advanced phosphate-based cathode material for lithium-ion batteries. Commonly represented by the general formula LiFe\u2081\u208b\u2093Mn\u2093PO\u2084, LMFP combines the structural stability and safety characteristics of lithium iron phosphate (LFP) with the higher operating voltage potential of lithium manganese phosphate (LMP).<\/p>\n<p>By adjusting the manganese-to-iron ratio, particle size, morphology, and carbon-coating structure, LMFP can be engineered to achieve a balance of energy density, thermal stability, cycle life, and cost efficiency. It is being increasingly investigated for next-generation lithium-ion batteries used in electric vehicles, energy storage systems, power tools, and other high-performance applications.<\/p>\n<h2><span style=\"font-size: 14pt;\">LMFP Powder Properties<\/span><\/h2>\n<table style=\"border-collapse: collapse; width: 100%; height: 221px;\">\n<tbody>\n<tr style=\"height: 29px;\">\n<td style=\"width: 50%; height: 29px;\"><strong>Property<\/strong><\/td>\n<td style=\"width: 50%; height: 29px;\"><strong>Description<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Material<\/td>\n<td style=\"width: 50%; height: 24px;\">Lithium Manganese Iron Phosphate<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Abbreviation<\/td>\n<td style=\"width: 50%; height: 24px;\">LMFP<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">General Formula<\/td>\n<td style=\"width: 50%; height: 24px;\">LiMn\u2093Fe\u2081\u208b\u2093PO\u2084<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Appearance<\/td>\n<td style=\"width: 50%; height: 24px;\">Gray powder<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Crystal Structure<\/td>\n<td style=\"width: 50%; height: 24px;\">Olivine-type phosphate structure<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Water Solubility<\/td>\n<td style=\"width: 50%; height: 24px;\">Generally insoluble or very slightly soluble in water<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Thermal Stability<\/td>\n<td style=\"width: 50%; height: 24px;\">High thermal and structural stability<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 50%; height: 24px;\">Typical Application<\/td>\n<td style=\"width: 50%; height: 24px;\">Lithium-ion battery cathode material<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2><span style=\"font-size: 14pt;\">Key Advantages of LMFP Powder<\/span><\/h2>\n<ul>\n<li>Higher Operating Voltage<\/li>\n<li>Excellent Thermal Stability<\/li>\n<li>Improved Safety<\/li>\n<li>Long-Term Cycling Potential<\/li>\n<li>Cost-Effective Chemistry<\/li>\n<li>Flexible Composition Design<\/li>\n<\/ul>\n<h2><span style=\"font-size: 14pt;\">Specifications of LMFP Powder<\/span><\/h2>\n<table style=\"border-collapse: collapse; width: 100%; height: 397px;\">\n<tbody>\n<tr style=\"height: 21px;\">\n<td style=\"width: 40%; text-align: center; height: 45px;\" colspan=\"2\" rowspan=\"2\"><strong>Item<\/strong><\/td>\n<td style=\"width: 60%; text-align: center; height: 21px;\" colspan=\"3\"><strong>Standard<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\"><strong>LiMn0.2Fe0.8PO4<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\"><strong>LiMn0.6Fe0.4PO4<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\"><strong>LiMn0.7Fe0.3PO4<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 120px;\" rowspan=\"5\"><strong>Element Content<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">Li (wt%)<\/td>\n<td style=\"width: 20%; height: 24px;\">4.3\u00b10.2<\/td>\n<td style=\"width: 20%; height: 24px;\">4.4\u00b10.3<\/td>\n<td style=\"width: 20%; height: 24px;\">4.4\u00b10.3<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">Fe (wt%)<\/td>\n<td style=\"width: 20%; height: 24px;\">27.6\u00b11.5<\/td>\n<td style=\"width: 20%; height: 24px;\">14.3\u00b11.0<\/td>\n<td style=\"width: 20%; height: 24px;\">7.1\u00b11.0<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">Mn (wt%)<\/td>\n<td style=\"width: 20%; height: 24px;\">6.9\u00b10.4<\/td>\n<td style=\"width: 20%; height: 24px;\">21.0\u00b11.0<\/td>\n<td style=\"width: 20%; height: 24px;\">28.0\u00b11.0<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">P (wt%)<\/td>\n<td style=\"width: 20%; height: 24px;\">19.3\u00b10.5<\/td>\n<td style=\"width: 20%; height: 24px;\">19.6\u00b11.0<\/td>\n<td style=\"width: 20%; height: 24px;\">19.6\u00b11.0<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">C (wt%)<\/td>\n<td style=\"width: 20%; height: 24px;\">1.5\u00b10.2<\/td>\n<td style=\"width: 20%; height: 24px;\">2.5\u00b10.5<\/td>\n<td style=\"width: 20%; height: 24px;\">2.5\u00b10.5<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 88px;\" rowspan=\"4\"><strong>Size (Primary Particle)<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">D10 (\u03bcm)<\/td>\n<td style=\"width: 20%; height: 24px;\">0.1~0.3<\/td>\n<td style=\"width: 20%; height: 24px;\">0.5~0.8<\/td>\n<td style=\"width: 20%; height: 24px;\">0.5~0.8<\/td>\n<\/tr>\n<tr style=\"height: 16px;\">\n<td style=\"width: 20%; height: 16px;\">D50 (\u03bcm)<\/td>\n<td style=\"width: 20%; height: 16px;\">0.3~0.7<\/td>\n<td style=\"width: 20%; height: 16px;\">1.2~1.6<\/td>\n<td style=\"width: 20%; height: 16px;\">1.2~1.6<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">D90 (\u03bcm)<\/td>\n<td style=\"width: 20%; height: 24px;\">6~7<\/td>\n<td style=\"width: 20%; height: 24px;\">&lt;5<\/td>\n<td style=\"width: 20%; height: 24px;\">&lt;7<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">D97 (\u03bcm)<\/td>\n<td style=\"width: 20%; height: 24px;\">13~14<\/td>\n<td style=\"width: 20%; height: 24px;\">&lt;9<\/td>\n<td style=\"width: 20%; height: 24px;\">&lt;9<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\" colspan=\"2\"><strong>PH<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">8.0~9.0<\/td>\n<td style=\"width: 20%; height: 24px;\">7.0~8.0<\/td>\n<td style=\"width: 20%; height: 24px;\">8.0~9.0<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\" colspan=\"2\"><strong>Moisture Content (ppm)<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">\u22641000<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2264800<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2264800<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 48px;\" rowspan=\"2\"><strong>Initial Discharge Capacity<\/strong><br \/>\n<strong>(2.5-4.5V VS Li)<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">0.1C (mAh\/g)<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265155<\/td>\n<td style=\"width: 20%; height: 24px;\">&#8211;<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265155<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">0.2C (mAh\/g)<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265150<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265155<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265150<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 48px;\" rowspan=\"2\"><strong>C-Rate<\/strong><\/td>\n<td style=\"width: 20%; height: 24px;\">0.3C (mAh\/g)<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265150<\/td>\n<td style=\"width: 20%; height: 24px;\">&#8211;<\/td>\n<td style=\"width: 20%; height: 24px;\">&#8211;<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 20%; height: 24px;\">0.5C (mAh\/g)<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265110<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265145<\/td>\n<td style=\"width: 20%; height: 24px;\">\u2265145<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2><span style=\"font-size: 14pt;\">Electrochemical Performance<\/span><\/h2>\n<p>LMFP offers an attractive balance between energy density and safety.<\/p>\n<p>Compared with LiFePO\u2084, LMFP generally provides a higher average operating voltage, while maintaining the fundamental advantages of phosphate-based cathode materials. Depending on composition, morphology, carbon coating, particle size, and electrode formulation, LMFP can deliver a practical specific capacity typically in the range of approximately 120\u2013160 mAh\/g.<\/p>\n<p>Its electrochemical performance is strongly influenced by manganese content and material engineering. In particular, the relatively low intrinsic electronic and lithium-ion conductivity of LMFP makes particle-size control, carbon coating, and conductive-network design important factors in achieving high-rate performance.<\/p>\n<h2><span style=\"font-size: 14pt;\">LMFP vs. LFP<\/span><\/h2>\n<table style=\"border-collapse: collapse; width: 100%; height: 243px;\">\n<tbody>\n<tr style=\"height: 27px;\">\n<td style=\"width: 33.3333%; height: 27px;\"><strong>Property<\/strong><\/td>\n<td style=\"width: 33.3333%; height: 27px;\"><strong>LMFP<\/strong><\/td>\n<td style=\"width: 33.3333%; height: 27px;\"><strong>LFP<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Main Composition<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">LiMn\u2093Fe\u2081\u208b\u2093PO\u2084<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">LiFePO\u2084<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Average Voltage<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Higher<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Lower<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Potential Energy Density<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Higher<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Moderate<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Thermal Stability<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Excellent<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Excellent<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Safety<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Excellent<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Excellent<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Cycle Life<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">High, composition-dependent<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Excellent<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Raw Material Cost<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Competitive<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Competitive<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Electronic Conductivity<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Relatively low; conductive modification often required<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">Relatively low; conductive modification often required<\/td>\n<\/tr>\n<tr style=\"height: 24px;\">\n<td style=\"width: 33.3333%; height: 24px;\">Typical Applications<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">EVs, ESS, power batteries<\/td>\n<td style=\"width: 33.3333%; height: 24px;\">EVs, ESS, power tools<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2><span style=\"font-size: 14pt;\">Applications of Lithium Iron Manganese Phosphate Powder<\/span><\/h2>\n<ul>\n<li><strong>Electric Vehicle Batteries:<\/strong> LMFP is being developed as a next-generation cathode material for electric vehicle batteries where higher energy density than LFP, thermal stability, long service life, and cost control are important.<\/li>\n<li><strong>Energy Storage Systems: <\/strong>The combination of safety, cost competitiveness, and cycling stability makes LMFP attractive for stationary energy storage, including renewable-energy storage and grid-scale battery systems.<\/li>\n<li><strong>Hybrid Electric Vehicles: <\/strong>LMFP can be considered for hybrid and other high-power battery systems that require reliable cycling performance and strong thermal stability.<\/li>\n<li><strong>Power Tools: <\/strong>Its combination of safety, durability, and cost efficiency makes LMFP a potential cathode chemistry for rechargeable power tools and other high-power portable equipment.<\/li>\n<li><strong>Battery Research and Development: <\/strong>LMFP powder is also suitable for cathode material research, electrode formulation, coin-cell testing, pouch-cell development, and battery chemistry optimization.<\/li>\n<\/ul>\n<h2><span style=\"font-size: 14pt;\">LMFP Powder for Research and Industrial Applications<\/span><\/h2>\n<p>VIMATERIAL supplies LMFP powder for battery material research, cathode development, and industrial applications. Material characteristics can be tailored according to application requirements, including:<\/p>\n<ul>\n<li>Mn\/Fe composition ratio<\/li>\n<li>Particle size and particle-size distribution<\/li>\n<li>Powder morphology<\/li>\n<li>Specific surface area<\/li>\n<li>Carbon coating or conductive modification<\/li>\n<li>Tap density<\/li>\n<li>Moisture content<\/li>\n<li>Electrochemical performance<\/li>\n<li>Packaging and quantity<\/li>\n<\/ul>\n<p>Custom specifications may be available according to your battery chemistry, electrode formulation, and processing requirements.<\/p>\n<h2><span style=\"font-size: 14pt;\">Handling and Storage<\/span><\/h2>\n<p>Handled in a dry, clean, and well-ventilated environment. Keep the material tightly sealed and protected from moisture, contamination, and excessive heat. For long-term storage, use moisture-resistant packaging and avoid unnecessary exposure to ambient humidity.<\/p>\n<p>When handling fine powders, appropriate personal protective equipment and dust-control procedures should be followed in accordance with the applicable SDS and workplace safety requirements.<\/p>\n<h2><span style=\"font-size: 14pt;\">Why Choose VIMATERIAL?<\/span><\/h2>\n<ul>\n<li>Battery-grade material supply<\/li>\n<li>Custom Mn\/Fe composition available<\/li>\n<li>Particle-size and morphology customization<\/li>\n<li>Research and industrial quantities<\/li>\n<li>Technical support for material selection<\/li>\n<li>Moisture-resistant packaging<\/li>\n<li>Suitable for battery R&amp;D and cathode development<\/li>\n<li>Custom specifications available upon request<\/li>\n<\/ul>\n<h2><span style=\"font-size: 14pt;\">Frequently Asked Questions<\/span><\/h2>\n<p><strong>Q1. What is LMFP powder?<\/strong><\/p>\n<p>LMFP powder is a lithium-ion battery cathode material based on lithium manganese iron phosphate, generally represented by LiMn\u2093Fe\u2081\u208b\u2093PO\u2084. It combines the safety and structural stability of LFP with the higher voltage potential associated with manganese substitution.<\/p>\n<p><strong>Q2. What is the difference between LMFP and LFP?<\/strong><\/p>\n<p>The primary difference is the partial substitution of iron with manganese. LMFP generally provides a higher operating voltage and potentially higher energy density than LFP while retaining many of LFP&#8217;s safety and thermal-stability advantages.<\/p>\n<p><strong>Q3. Is LMFP suitable for electric vehicle batteries?<\/strong><\/p>\n<p>Yes. LMFP is being actively investigated for EV applications because it can provide a useful balance of energy density, safety, cycle life, and material cost.<\/p>\n<p><strong>Q4. Does LMFP require carbon coating?<\/strong><\/p>\n<p>LMFP has relatively low intrinsic electronic conductivity. Carbon coating and\/or other conductive modifications are therefore commonly used to improve electronic conductivity and rate performance.<\/p>\n<p><strong>Q5. Can LMFP powder be customized?<\/strong><\/p>\n<p>Yes. Depending on the application, parameters such as Mn\/Fe ratio, particle size, morphology, carbon coating, surface area, and packaging can be discussed according to specific technical requirements.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Lithium manganese iron phosphate powder is an advanced phosphate-based cathode material for lithium-ion batteries. Commonly represented by the general formula LiFe\u2081\u208b\u2093Mn\u2093PO\u2084, LMFP combines the structural stability and safety characteristics of lithium iron phosphate (LFP) with the higher operating voltage potential of lithium manganese phosphate (LMP). By adjusting the manganese-to-iron ratio, particle size, morphology, and carbon-coating [&hellip;]<\/p>\n","protected":false},"featured_media":1051220,"comment_status":"open","ping_status":"closed","template":"","meta":{"_acf_changed":false},"product_brand":[],"product_cat":[88],"product_tag":[],"class_list":["post-998922","product","type-product","status-publish","has-post-thumbnail","product_cat-battery-materials","first","instock","shipping-taxable","product-type-variable"],"acf":[],"_links":{"self":[{"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/product\/998922","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/comments?post=998922"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/media\/1051220"}],"wp:attachment":[{"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/media?parent=998922"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/product_brand?post=998922"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/product_cat?post=998922"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/vimaterial.de\/en\/wp-json\/wp\/v2\/product_tag?post=998922"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}